Allylic And Vinylic Carbocation Stability

A vinylic carbocation which has an empirical formula of c h is a carbocation that has a positive charge only on the alkene carbon atom. As the allyl cation has only one substituent on the carbon bearing the positive charge it is primarily allylic carbocation. We know that the rate limiting step of an s n 1 reaction is the first step formation of the this carbocation intermediate.

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